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Radio-gas-chromatographic investigation of sotope exchange reactions between inorganic halides

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Abstract

Gas-chromatographic behavior of halides of arsenic and phosphorus and isotope exchange reactions among these species were investigated by means of radiotracer techniques. The halides studied in the present work include AsCl3, AsBr3, PBr3,76AsBr3,76AsCl3, and As82Br3. It was demonstrated that the rapid isotope exchange of arsenic and bromine took place in the binary systems: AsBr3−AsCl3 and AsBr3−PBr3, in the course of the gas-chromatographic separation process.

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References

  1. Y. MAKIDE, N. SAITO, IUPAC International Congress on Analytical Chemistry, Kyoto, 1972, p. 99.

  2. Y. MAKIDE, N. SAITO, Bull. Chem. Soc. Japan, 45 (1972) 968.

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  3. J. TADMOR, J. Inorg. Nucl. Chem., 23 (1961) 158; Anal. Chem., 36 (1964) 1565.

    Article  CAS  Google Scholar 

  4. H. ELIAS, Advances in Chromatography, (Eds J. C. GIDDINGS, R. A. KELLER), Marcel Dekker, New York, Vol. 7, 1968, p. 243.

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  5. Y. MAKIDE, N. SAITO (to be published).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, The University of Tokyo, 7-3-1 Hongo, 113, Tokyo, (Japan)

    Y. Makide & N. Saito

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  1. Y. Makide
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  2. N. Saito
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Makide, Y., Saito, N. Radio-gas-chromatographic investigation of sotope exchange reactions between inorganic halides. J. Radioanal. Chem. 36, 113–118 (1977). https://doi.org/10.1007/BF02516258

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  • DOI: https://doi.org/10.1007/BF02516258

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