Abstract
Instrumental neutron activation analysis (INAA) methods have been developed for the simultaneous determination of multielement concentrations in both particulate and soluble fractions of atmospheric wet precipitation (AWP). Samples of AWP collected across Canada by Canadian Network for Sampling Precipitation (CANSAP) have been analyzed. The INAA method involves four sequential irradiations and counting after five different decay periods for measuring Ag, Al, As, Au, Ba, Br, Ca, Ce, Cl, Co, Cr, Cu, Dy, Fe, Hf, Hg, I, K, La, Mg, Mn, Na, Rb, Sb, Sc, Se, Sm, Sr, Ti V and Zn. Precision and accuracy of the INAA methods have been evaluated, and detection limits have been calculated.
Similar content being viewed by others
References
J. NORDO, Water, Air and Soil Poll., 6 (1976) 199.
J. WHELPDALE, Atmos. Environ., 12 (1978) 661.
R. W. SHAW, Environ. Sci. Technol., 13 (1979) 406.
G. E. LIKENS, F. H. BORMANN, Science, 184 (1974) 1176.
R. E. NEWELL, Scient. Amer., 223 (1970) 32.
A. C. CHAMBERLAIN, Int. J. Air Poll., 3 (1960) 63.
A. L. LAZRUS, E. LORANGE, J. P. LODGE, Environ. Sci. Technol., 4 (1970) 55.
J. SLANINA, W. A. LINGERAK, L. BERGMAN, Z. Anal. Chem., 280 (1976) 365.
V. M. DROZDOVA, E. P. MAKHON'KO, J. Geophys. Res., 75 (1970) 3610.
R. C. HARRIS, H. H. WILLIAMS, J. Appl. Met., 8 (1969) 299.
J. BOGEN, Atmos. Environ., 8 (1974) 835.
P. A. CAWSE, Atom. Ener. Res. Est., Harwell, U. K., AERE-R7669, 1974.
W. F. MERRITT, Proc. Intern. Symp. Measurement, Detection and Control of Environmental Pollutants, IAEA, Vienna (1976) p. 75.
J. B. LUTEN, Netherlands Ener. Res. Found., Rept. ECN-20, 1977.
P. SCHUTYSER, W. MAENHAUT, R. DAMS, Anal. Chim. Acta, 100 (1978) 75.
J. SLANINA, J. J. MOLS, J. H. BAARD, H. A. VAN DER SLOOT, J. G. VAN RAAPHORST, Intern. J. Environ. Anal. Chem., 7 (1979) 161.
D. E. RYAN, D. C. STUART, A. CHATTOPADHYAY, Anal. Chim. Acta, 100 (1978) 87.
C. M. LEDERER, V. S. SHIRLEY (Eds), Table of Isotopes, 7 th. ed., Wiley-Interscience, New York, 1978.
R. E. TOUT, A. CHATT, Anal. Chim. Acta, 118 (1980) 341.
A. CHATTOPADHYAY, K. N. DESILVA, Trans. Am. Nucl. Soc., 32 (1979) 185.
N. M. SPYROU, S. A. KERR, J. Radioanal. Chem., 48 (1979) 169.
S. A. KERR, N. M. SPYROU, J. Radioanal. Chem., 44 (1978) 159.
A. CHATT, K. N. DESILVA, J. HOLZBECHER, D. C. STUART, R. E. TOUT, D. E. RYAN, Can. J. Chem. (in press).
A. CHATT, K. N. DESILVA, Proc. 4th. Intern. Conf. Nuclear Methods in Environmental and Energy Research, J. R. VOGT (Ed.), Univ. of Missouri-Columbia; USA (in press).
A. CHATT, K. N. DESILVA, R. E. TOUT, Proc. Ist. Ann. Conf. Can. Nucl. Soc., W. PASKIEVICI (Ed.), Vol. 1 (1980) p. 337.
K. N. DESILVA, Ph. D. thesis, Dalhousie University, 1981.
R. E. TOUT, A. CHATT, Trans. Am. Nucl. Soc., 33 (1979) 233.
R. E. TOUT, A. CHATT, Anal. Chim. Acta (in press).
K. M. ELLIS, A. CHATTOPADHYAY, Anal. Chem., 51 (1979) 942.
A. CHATT, A. I. KULATHILAKE, Proc. NATO Advanced Research Institute on Trace Metals in Seawater, Plenum Press, N.Y. (in press).
S. H. HARRISON, P. D. LEFLEUR, W. H. ZOLLER, Anal. Chem., 47 (1975) 1685.
National Bureau of Standards, Certificate of Analysis, Standard Reference Material 1635, Subbituminous Coal, Washington, D. C., 1978.
M. S. GERMANI, I. GOKMEN, A. C. SIGLEO, G. S. KOWALCZYK, I. OLMEZ, A. M. SMALL, D. L. ANDERSON, M. P. FAILEY, M. C. GULOVALI, C. E. CHOQUETTE, E. A. LEPEL, G. E. GORDON, W. H. ZOLLER, Anal. Chem., 52 (1980) 240.
M. R. SANDEMAN, A. CHATT, to be published.
L. A. CURRIE, Anal. Chem., 40 (1968) 586.
Nuclepore Corp., Catalog Lab., 50, CA, USA, 1980.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hamilton, E.P., Chatt, A. Determination of trace elements in atmospheric wet precipitation by instrumental neutron activation analysis. J. Radioanal. Chem. 71, 29–45 (1982). https://doi.org/10.1007/BF02516139
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02516139