Abstract
As a contribution to the neutron activation assay of the reactor grade aluminium, a number of elements have been investigated by a developed analytical scheme. With the performance of ion-exchange chromatography combined with the precipitation techniques, ppm concentration (or even less) of arsenic, antimony, calcium, copper, mercury, selenium and strontium contaminants were demonstrated with good reproducibility. Whenever possible, some of the elements analyzed by radioactivation and proved to be present in high concentration levels were assayed by other standard analytical methods.
Similar content being viewed by others
References
U.A.R. Specifications, Raw Aluminum and its Products, Egyptian Standard Specification Dept., Ministry of Industry, Cairo, Egypt, EOS/5/403, 1963.
S. K. Khasnobis,Indian J. Appl. Chem., 25 (1962) 77.
Metals Handbook, Amer. Soc. for Metals, 1948, p. 840.
Analytical Methods for Atomic Absorption Spectrophotometry, Perkin-Elmer Corp., Connecticut, U.S.A. 1968.
O. Johansen, E. Steinnes,Intern. J. Appl. Radiation Isotopes, 20 (1969) 751.
J. Starý, The Solvent Extraction of Metal Chelates, Pergamon, London, 1964.
D. N. Sunderman, C. W. Townley, The Radiochemistry of Calcium, Strontium and Barium, NAS-NS, 3010, 1960.
D. F. Covell,Anal. Chem., 31 (1959) 1785.
R. Mavrodineanu, Analytical Flame Spectroscopy, Macmillan, Toronto, 1970.
A.S.T.M. Standards, Chemical Analysis of Metals American Society for Testing and Materials, Philadelphia, U. S. A., Part 32, 1963, p. 164.
G. Charlot, D. Bézier, Quantitative Inorganic Analysis, Wiley, New York, 1957, p. 351.E. B. Sandell, Colorimetric Determination of Traces of Metals, Interscience, New York, 3rd ed., 1959.
A. I. Vogel, Quantitative Inorganic Analysis, Longmans, 3rd ed., London, 1961, p. 514.
W. W. Scott, Standard Methods of Chemical Analysis, New York, 5th ed., Vol. 1, 1939, p. 287.J. W. Mellor, A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Longmans, London, Vol. 5, 1960, p. 557.
H. J. M. Bowen, D. Gibbons, Radioactivation Analysis, Clarendon, Oxford, 1963, p. 122.
Y. Marcus, Israel Atomic Energy Comm. Rept., IA-1087, 1966.
L. I. Katzin, E. Gebert,J. Chem. Soc., (1953) 801.T. V. Arden, G. A. Wood,J. Chem. Soc., (1956) 1596.T. V. Arden, M. Rowley,J. Chem. Soc., (1957) 1709.J. Korkish, G. E. Janauer,Talanta, 9 (1962) 979.
Y. Marcus,J. Phys. Chem., 63 (1959) 1000.
A. E. Martell, L. G. Sillén, Stability Constants of Metal Ion Complexes, Spec. Publ. No. 17, The Chemical Society, London, 1964.
M. Kobayashi, T. Swai,Tokyo Metropolitan Isotope Centre, Ann. Rept., 1 (1962) 25.
J. Gaittet, P. Albert,Compte Rend., 247 (1958) 1861.
W. D. Mackintosh,Anal. Chem., 32 (1960) 1272.
G. Chaudron,Rec. Trav. Chim., 79 (1960) 502.
P. Albert, N. Deschaps, L. Fournet, M. Deyris, Seminar on the Practical Applications of Short-lived Radioisotopes Produced in Small Research Reactors, IAEA, Vienna, Nov. 5, 1962, Paper No. SM-32/31.P. Albert, J. Gaittet, Radioactive Isotopes in the Physical Sciences and Industry, IAEA. Vienna, Vol. 2, 1962, p. 243.P. Albert, M. Cuypers, A. Lesbats, E. Mignonsin, Proc. Intern. Conf. on Modern Trends in Activation Analysis, Texas, 1965, p. 310.
F. Girardi, J. Pauly, Nucl. Energy Conf, Milan, Dec. 1961 (Conf.-140-1; EUR 306. i).F. Girardi, R. Pietra,Anal. Chem., 35 (1963) 173.
B. Chinaglia, R. Malvano,Energia Nucleare, 8 (1961) 571.S. G. Prussin, J. A. Harris, J. M. Hollander,Anal. Chem., 37 (1965) 1127.F. Girardi, G. Guzzi, J. Pauly,Anal. Chem., 37 (1965) 1085.M. P. Menon, A. P. Rainosek, R. E. Ainerdi,Nucl. Appl., 2 (1966) 335.
M. Kakaš, L. Marinkov, R. Drašković,Radiochim. Acta, 13 (1970) 75.
Ke, Chiung-Hei, Cheng, Hwa-Sheng,J. Chinese Chem. Soc. (Taiwan), 12 (1965) 39.
D. Monnier, G. Prod'hom,Anal. Chim. Acta, 30 (1964) 358.
S. A. Reynolds, W. T. Mullins,Intern. J. Appl. Radiation Isotopes, 14 (1963) 421.O. T. Høgdahl, Radiochemical Methods of Analysis, IAEA, Salzburg, Oct. 1964, Proc. Series, Vienna, 1965, p. 23.
J. Brzosko, P. Decowski, Z. Wilhelmi,Nucl. Phys., 45 (1963) 579.Yu, Yu-wen, Chicago, Illinois Inst. of Tech., 1966, Ph. D. Thesis;Nucl. Sci. Abstr., 21 (1967) 46776.
H. K. El-Shamy, A. A. Abdel-Rassoul, T. Z. Bishay, Proc. 3rd Intern. Conf. Peaceful Uses Atomic Energy, Geneva, Vol. 15, 1965, p. 484.H. K. El-Shamy, A. A. Abdel-Rassoul, T. Z. Bishay,J. Isot. Radiat. Technol., 2 (1965) 349.T. Z. Bishay,Anal Chem., 10 (1972) 51.
Nuclear Fuel in Canada, Atomic Energy of Canada Ltd., Chalk River, Ontario, 1951.
G. H. Morrison, Trace Analysis (Physical Methods), Interscience, New York, 1965.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bishay, T.Z. Purity control of aluminium metal. J. Radioanal. Chem. 13, 87–105 (1973). https://doi.org/10.1007/BF02514113
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02514113