Skip to main content
Log in

Purity control of aluminium metal

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

As a contribution to the neutron activation assay of the reactor grade aluminium, a number of elements have been investigated by a developed analytical scheme. With the performance of ion-exchange chromatography combined with the precipitation techniques, ppm concentration (or even less) of arsenic, antimony, calcium, copper, mercury, selenium and strontium contaminants were demonstrated with good reproducibility. Whenever possible, some of the elements analyzed by radioactivation and proved to be present in high concentration levels were assayed by other standard analytical methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. U.A.R. Specifications, Raw Aluminum and its Products, Egyptian Standard Specification Dept., Ministry of Industry, Cairo, Egypt, EOS/5/403, 1963.

  2. S. K. Khasnobis,Indian J. Appl. Chem., 25 (1962) 77.

    CAS  Google Scholar 

  3. Metals Handbook, Amer. Soc. for Metals, 1948, p. 840.

  4. Analytical Methods for Atomic Absorption Spectrophotometry, Perkin-Elmer Corp., Connecticut, U.S.A. 1968.

  5. O. Johansen, E. Steinnes,Intern. J. Appl. Radiation Isotopes, 20 (1969) 751.

    Article  CAS  Google Scholar 

  6. J. Starý, The Solvent Extraction of Metal Chelates, Pergamon, London, 1964.

    Google Scholar 

  7. D. N. Sunderman, C. W. Townley, The Radiochemistry of Calcium, Strontium and Barium, NAS-NS, 3010, 1960.

  8. D. F. Covell,Anal. Chem., 31 (1959) 1785.

    Article  CAS  Google Scholar 

  9. R. Mavrodineanu, Analytical Flame Spectroscopy, Macmillan, Toronto, 1970.

    Google Scholar 

  10. A.S.T.M. Standards, Chemical Analysis of Metals American Society for Testing and Materials, Philadelphia, U. S. A., Part 32, 1963, p. 164.

  11. G. Charlot, D. Bézier, Quantitative Inorganic Analysis, Wiley, New York, 1957, p. 351.E. B. Sandell, Colorimetric Determination of Traces of Metals, Interscience, New York, 3rd ed., 1959.

    Google Scholar 

  12. A. I. Vogel, Quantitative Inorganic Analysis, Longmans, 3rd ed., London, 1961, p. 514.

    Google Scholar 

  13. W. W. Scott, Standard Methods of Chemical Analysis, New York, 5th ed., Vol. 1, 1939, p. 287.J. W. Mellor, A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Longmans, London, Vol. 5, 1960, p. 557.

    Google Scholar 

  14. H. J. M. Bowen, D. Gibbons, Radioactivation Analysis, Clarendon, Oxford, 1963, p. 122.

    Google Scholar 

  15. Y. Marcus, Israel Atomic Energy Comm. Rept., IA-1087, 1966.

  16. L. I. Katzin, E. Gebert,J. Chem. Soc., (1953) 801.T. V. Arden, G. A. Wood,J. Chem. Soc., (1956) 1596.T. V. Arden, M. Rowley,J. Chem. Soc., (1957) 1709.J. Korkish, G. E. Janauer,Talanta, 9 (1962) 979.

  17. Y. Marcus,J. Phys. Chem., 63 (1959) 1000.

    Article  CAS  Google Scholar 

  18. A. E. Martell, L. G. Sillén, Stability Constants of Metal Ion Complexes, Spec. Publ. No. 17, The Chemical Society, London, 1964.

    Google Scholar 

  19. M. Kobayashi, T. Swai,Tokyo Metropolitan Isotope Centre, Ann. Rept., 1 (1962) 25.

    Google Scholar 

  20. J. Gaittet, P. Albert,Compte Rend., 247 (1958) 1861.

    CAS  Google Scholar 

  21. W. D. Mackintosh,Anal. Chem., 32 (1960) 1272.

    Article  CAS  Google Scholar 

  22. G. Chaudron,Rec. Trav. Chim., 79 (1960) 502.

    Article  CAS  Google Scholar 

  23. P. Albert, N. Deschaps, L. Fournet, M. Deyris, Seminar on the Practical Applications of Short-lived Radioisotopes Produced in Small Research Reactors, IAEA, Vienna, Nov. 5, 1962, Paper No. SM-32/31.P. Albert, J. Gaittet, Radioactive Isotopes in the Physical Sciences and Industry, IAEA. Vienna, Vol. 2, 1962, p. 243.P. Albert, M. Cuypers, A. Lesbats, E. Mignonsin, Proc. Intern. Conf. on Modern Trends in Activation Analysis, Texas, 1965, p. 310.

  24. F. Girardi, J. Pauly, Nucl. Energy Conf, Milan, Dec. 1961 (Conf.-140-1; EUR 306. i).F. Girardi, R. Pietra,Anal. Chem., 35 (1963) 173.

  25. B. Chinaglia, R. Malvano,Energia Nucleare, 8 (1961) 571.S. G. Prussin, J. A. Harris, J. M. Hollander,Anal. Chem., 37 (1965) 1127.F. Girardi, G. Guzzi, J. Pauly,Anal. Chem., 37 (1965) 1085.M. P. Menon, A. P. Rainosek, R. E. Ainerdi,Nucl. Appl., 2 (1966) 335.

    CAS  Google Scholar 

  26. M. Kakaš, L. Marinkov, R. Drašković,Radiochim. Acta, 13 (1970) 75.

    Google Scholar 

  27. Ke, Chiung-Hei, Cheng, Hwa-Sheng,J. Chinese Chem. Soc. (Taiwan), 12 (1965) 39.

    Google Scholar 

  28. D. Monnier, G. Prod'hom,Anal. Chim. Acta, 30 (1964) 358.

    Article  CAS  Google Scholar 

  29. S. A. Reynolds, W. T. Mullins,Intern. J. Appl. Radiation Isotopes, 14 (1963) 421.O. T. Høgdahl, Radiochemical Methods of Analysis, IAEA, Salzburg, Oct. 1964, Proc. Series, Vienna, 1965, p. 23.

    Article  Google Scholar 

  30. J. Brzosko, P. Decowski, Z. Wilhelmi,Nucl. Phys., 45 (1963) 579.Yu, Yu-wen, Chicago, Illinois Inst. of Tech., 1966, Ph. D. Thesis;Nucl. Sci. Abstr., 21 (1967) 46776.

    Article  CAS  Google Scholar 

  31. H. K. El-Shamy, A. A. Abdel-Rassoul, T. Z. Bishay, Proc. 3rd Intern. Conf. Peaceful Uses Atomic Energy, Geneva, Vol. 15, 1965, p. 484.H. K. El-Shamy, A. A. Abdel-Rassoul, T. Z. Bishay,J. Isot. Radiat. Technol., 2 (1965) 349.T. Z. Bishay,Anal Chem., 10 (1972) 51.

  32. Nuclear Fuel in Canada, Atomic Energy of Canada Ltd., Chalk River, Ontario, 1951.

  33. G. H. Morrison, Trace Analysis (Physical Methods), Interscience, New York, 1965.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bishay, T.Z. Purity control of aluminium metal. J. Radioanal. Chem. 13, 87–105 (1973). https://doi.org/10.1007/BF02514113

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02514113

Keywords

Navigation