Skip to main content
SpringerLink
Log in

Electrochemical oxidation of sulfodifluoroacetic acid in the presence of halogens

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

The electrochemical oxidation of sulfodifluoroacetic acid (HOSO2CF2CO2H) in the presence of Cl2 or Br2 gives halodifluoromethanesulfonic acid. The anodic oxidation of sulfodifluoromethanecarboxylate ion to form the sulfodifluoromethyl radical as an intermediate is proposed as the rate-determining step.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. A. Sokol'skii and I. L. Knunyants,Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1289–1294 (1967).

    Google Scholar 

  2. G. S. Krasnikova, L. S. German, and I. L. Knunyants,Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 2127 (1972).

    Google Scholar 

  3. V. A. Grinberg, V. F. Cherstkov, S. R. Sterlin, et al.,Izv. Akad. Nauk SSSR, Ser. Khim., No. 8 1841–1844 (1990).

    Google Scholar 

  4. M. Beiser and H. Lund (ed.),Organic Electrochemistry [Russian translation], Khimiya, Moscow (1988)

    Google Scholar 

  5. N. D. Volkov, V. P. Nazaretian, and L. M. Yagupol'skii (Yagupolskii),Synthesis, No. 12, 972–974 (1979).

    Article  Google Scholar 

  6. L. V. Gurevich, G. V. Karachevtsev, et al.,Ionization Potentials and Electron Affinities [in Russian], Nauka, Moscow (1974).

    Google Scholar 

Download references

Authors
  1. E. A. Smertenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. D. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. D. Datsenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. V. Ignat'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanskaya ul., Kiev 253094, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 35, No. 4, pp. 246–248, July–August, 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smertenko, E.A., Volkov, N.D., Datsenko, S.D. et al. Electrochemical oxidation of sulfodifluoroacetic acid in the presence of halogens. Theor Exp Chem 35, 231–233 (1999). https://doi.org/10.1007/BF02511521

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02511521

Keywords

Search

Navigation