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Influence of encapsulation on the mechanism of thermal decomposition of hexacyanotransition metal complexes

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Abstract

It has been established that, in contrast to the pure substances, the thermal decomposition of hexacyanotransition metal complexes, encapsulated in the large cavities of faujasite, occurs by a hydrolytic mechanism. The composition of the gaseous products of the thermal decomposition depend on the characteristics of the localization of the cations in the inclusion compounds.

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Authors
  1. Yu. G. Gol'tsov
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  2. L. A. Matkovskaya
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  3. V. N. Solomakha
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  4. A. M. Glukhoi
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  5. P. N. Grabovyi
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  6. V. G. Golovatyi
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  7. V. G. Il'in
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Additional information

L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, Kiev 252039, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 35, No. 2, pp. 107–112, March–April, 1999.

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Gol'tsov, Y.G., Matkovskaya, L.A., Solomakha, V.N. et al. Influence of encapsulation on the mechanism of thermal decomposition of hexacyanotransition metal complexes. Theor Exp Chem 35, 103–108 (1999). https://doi.org/10.1007/BF02511498

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  • DOI: https://doi.org/10.1007/BF02511498

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