Theoretical and Experimental Chemistry

, Volume 35, Issue 2, pp 85–88 | Cite as

Catalytic activity and mechanism for the action of pyridines in the phenolysis of epichlorohydrin

  • I. V. Perepichka
  • E. N. Shved
  • Z. V. Stepanenko


The reactivity of 3-chlorophenol with epichlorohydrin in the presence of substituted pyridines was studied. The reaction orders relative to the reagents and catalyst were determined. Correlations permitting evaluation of the effect of structure and concentration of the catalyst were obtained. The catalysis mechanism was found.


Catalyst Concentration Epichlorohydrin Observe Rate Constant Chlorohydrin Catalytic Rate Constant 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    A. M. Paken,Epoxide Compounds and Expoxy Resins [in Russian], Goskhimizdat, Leningrad (1962).Google Scholar
  2. 2.
    M. F. Sorokin, L. N. Finyakin, and L. G. Shodé,Kinet. Katal.,27, No. 2, 321–328 (1976).Google Scholar
  3. 3.
    S. P. Kobzev, A. M. Romantsevich, and M. A. Simonov,Kinet. Katal.,36, No. 1, 1–6 (1995).Google Scholar
  4. 4.
    M. A. Tovmasyan, A. N. Zelenetskii, and V. V. Ivanov,Vysokomolekul. Soedin. A,25, No. 4, 862–870 (1983).Google Scholar
  5. 5.
    V. P. Nikol'skii et al. (eds.),Chemist's Handbook [in Russian], Vol. 2, Khimiya, Moscow-Leningrad (1971).Google Scholar
  6. 6.
    E. N. Shved, V. A. Ramenskaya, and I. V. Andrievskaya,Structure of Phenols and Their Reactivity with Epichlorohydrin [in Russian], Donetsk Univ., Donetsk (1994), dep. v. GNTB Ukrainy No. 2283 (December 5, 1994).Google Scholar
  7. 7.
    N. M. Émanuél' and D. G. Knorre,Textbook of Chemical Kinetics [in Russian], Vysshaya Shkola, Moscow (1969).Google Scholar
  8. 8.
    L. M. Litvinenko and N. M. Oleinik,Mechanism for the Action of Organic Catalysts [in Russian], Naukova Dumka, Kiev (1984).Google Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • I. V. Perepichka
  • E. N. Shved
  • Z. V. Stepanenko

There are no affiliations available

Personalised recommendations