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The C−C bond chain termination mechanism in Fischer-Tropsch synthesis on a Co/SiO2·Zr(IV) catalyst

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Abstract

Two forms of chain termination are considered: on account of hydrogenation of metal-carbon bonds in surface intermediates and because of the elimination of hydrogen, which leads to the formation of α-olefins as primary products.

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L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, Kiev 252039, Ukraine. Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 35, No. 1, pp. 44–49, January–February, 1999.

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Yakubovich, M.N., Chernobaev, I.I. & Pavlenko, N.V. The C−C bond chain termination mechanism in Fischer-Tropsch synthesis on a Co/SiO2·Zr(IV) catalyst. Theor Exp Chem 35, 45–51 (1999). https://doi.org/10.1007/BF02511127

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  • DOI: https://doi.org/10.1007/BF02511127

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