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Destruction reactions of some σ-derivatives of vanadium

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Abstract

The interactions of (Me3SiCH2)4V and (Me3SiCH2)3V·THF with cyclopentadiene have been studied. Me4Si and Cp2V were isolated. A scheme of the reactions was proposed which involves formation of unstable monocyclopentadienyl derivatives of vanadium.

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References

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1542–1544, August, 1997.

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Vyshinskaya, L.I., Korneva, S.P. & Kulikova, G.P. Destruction reactions of some σ-derivatives of vanadium. Russ Chem Bull 46, 1478–1480 (1997). https://doi.org/10.1007/BF02505692

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  • DOI: https://doi.org/10.1007/BF02505692

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