Abstract
Using negative ion mass spectrometry in the mode of resonance electron capture, it was found that the energy of dissociation of the S−S bond in dialkyl trisulfides is 0.6 eV smaller than that in their disulfide analogs and is equal to 1.9±0.1 eV.
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References
V. S. Shmakov, I. I. Furlei, N. K. Lyapina, V. I. Khvostenko, A. A. Polyakova, and G. A. Tolstikov,Dokl. Akad. Nauk SSSR, 1986,287, 139[Dokl. Chem., 1986 (Engl. Transl.)].
V. S. Shmakov, I. I. Furlei, N. K. Lyapina, V. I. Khvostenko. A. A. Polyakova, M. A. Parfenova, A. A. Vol'tsov, and G. A. Tolstikov,Neftekhim., 1986,26, 693[Petroleum Chem., 1986,26 (Engl. Transl.)].
A. M. Fakhriev, A. M. Mazgarov, and N. G. Galyautdinova,Khim. prom. [Chem. Industry], 1983, 344 (in Russian).
V. I. Khvostenko, inMass-spektrometriya otritsatel'nykh ionov v organicheskoi khimii [Mass spectrometry of Negative Ions in Organic Chemistry], Nauka, Moscow, 1981, 29; 47 (in Russian).
S. Moran and G. B. Ellison,J. Phys. Chem., 1988,92, 1794.
L. V. Gurvich, G. V. Karachevtsev, V. N. Kondrat'ev, Yu. A. Lebedev, V. A. Medvedev, V. K. Potapov, and Yu. S. Khodeev, inEnergii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu [Energies of Dissociation of Chemical Bonds. Ionization Patentials and Electron affinities], Nauka, Moscow, 1974, 95 (in Russian).
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1536–1537, August, 1997.
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Shmakov, V.S., Furley, I.I., Ulendeeva, A.D. et al. Resonance capture of electrons by molecules of dialkyl trisulfides. Russ Chem Bull 46, 1472–1473 (1997). https://doi.org/10.1007/BF02505689
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DOI: https://doi.org/10.1007/BF02505689