Abstract
Addition of dichlorocarbene to tricyclo[4.3.0.03,7]nona-4,8-diene (brexadiene) under conditions of phase transfer catalysis occurs from theexo side. Cyclopropyl-allyl rearrangement of intermediate chlorocyclopropanes yields tricyclo[5.4.0.03,8]undecadienes.
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Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1494–1497, August, 1997.
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Khoroshutin, A.V., Bobylyova, A.A., Pehk, T.I. et al. Addition of dichlorocarbene to tricyclo[4.3.0.03,7]nona-4,8-diene. Russ Chem Bull 46, 1430–1433 (1997). https://doi.org/10.1007/BF02505679
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DOI: https://doi.org/10.1007/BF02505679