Abstract
A series of di(NON-azoxy)formals and some relatedN-alkyl-N′-alkoxydiazeneN-oxides were prepared by the reaction ofN-nitrosohydroxylamine salts with dihaloalkanes. The dependence of the yield of di(methyl-NON-azoxy)formal on the reaction conditions and the nature of the cation was studied. The structure of di(methyl-NON-azoxy)formal and di(phenyl-NON-azoxy) formal as well as of the coppertert-butylnitrosohydroxylaminate was established by X-ray diffraction analysis.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1486–1493, August, 1997.
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Zyusin, I.N., Nechiporenko, G.N., Golovina, N.I. et al. Synthesis and structure of di(NON-azoxy)formals and some relatedN-alkyl-N′-alkoxydiazeneN-oxides. Russ Chem Bull 46, 1421–1429 (1997). https://doi.org/10.1007/BF02505678
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DOI: https://doi.org/10.1007/BF02505678