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Effect of temperature on the IR spectra of uncharged HCl-DMF complexes with a strong quasi-symmetrical H-bond

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The effect of temperature on the IR spectra of multiple attenuated internal reflection of uncharged HCl-DMF complexes formed by strong quasi-symmetrical H-bonds was studied. The optical density of individual bands of the complexes decreases as the temperature increases, and the background continuous absorption is almost independent of temperature in the whole frequency range (1200–2100 cm−1). It was concluded that strong quasi-symmetrical H-bonds are only slightly sensitive to temperature changes.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    I. S. Kislina & V. D. Maiorov

Authors
  1. I. S. Kislina
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  2. V. D. Maiorov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1461–1463, August, 1997.

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Kislina, I.S., Maiorov, V.D. Effect of temperature on the IR spectra of uncharged HCl-DMF complexes with a strong quasi-symmetrical H-bond. Russ Chem Bull 46, 1396–1398 (1997). https://doi.org/10.1007/BF02505673

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  • DOI: https://doi.org/10.1007/BF02505673

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