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Concerning the problem of temperature changes in the intensity of continuous absorption in the spectra of complexes with symmetric H-bond

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The effect of temperature on the spectra of anharmonic vibrations of complexes with symmetric H-bonds was simulated and considered using H3O2 − and H5O2 + ions as an example. The intensity of continuous absorption observed in the IR spectra of such types of complexes is virtually independent of temperature.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117071, Moscow, Russian Federation

    G. V. Yukhnevich & E. G. Tarakanova

Authors
  1. G. V. Yukhnevich
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  2. E. G. Tarakanova
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1447–1449, August, 1997.

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Yukhnevich, G.V., Tarakanova, E.G. Concerning the problem of temperature changes in the intensity of continuous absorption in the spectra of complexes with symmetric H-bond. Russ Chem Bull 46, 1383–1385 (1997). https://doi.org/10.1007/BF02505670

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  • DOI: https://doi.org/10.1007/BF02505670

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