Russian Chemical Bulletin

, Volume 46, Issue 11, pp 1862–1865 | Cite as

1H and13C NMR study of tin-containing sulfoxide, sulfimide, and sulfoximide

  • Yu. A. Kurskii
  • N. E. Stolyarova
  • V. I. Shcherbakov
  • I. A. Borisova
  • A. N. Ponomarev
Physical Chemistry
  • 23 Downloads

Abstract

Sulfoxide RS(O)R′ (1), sulfimide RS(=NSO2Ar)R′ (2), and sulfoximide RS(O)(=NSO2Ar)R′ (3) (R=Me3Sn(CH2)3, R′=n-C5H11, Ar=4-C6H4Cl) were investigated by1H and13C NMR spectroscopy. Unlike 3, compounds 1 and 2 have a cyclic structure due to the intramolecular donor-acceptor S→Sn interaction.

Key words

NMR spectroscopy structure trimethylstannyl-containing sulfoxide sulfimide sulfoximide 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • Yu. A. Kurskii
    • 1
  • N. E. Stolyarova
    • 1
  • V. I. Shcherbakov
    • 1
  • I. A. Borisova
    • 2
  • A. N. Ponomarev
    • 2
  1. 1.G. A. Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussian Federation
  2. 2.“Caprolactam” Co.DzerzhinskRussian Federation

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