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Synthesis of 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10 by cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with C6H5ZnCl catalyzed by palladium complexes

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Abstract

The cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with organozinc compounds catalyzed by palladium complexes was used to synthesize the first representative ofB-phenyl-substituted carboranes, 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10.

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References

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    L. I. Zakharkin, G. G. Zhigareva & E. V. Balagurova

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  1. L. I. Zakharkin
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  2. G. G. Zhigareva
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  3. E. V. Balagurova
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No: 6, pp. 1253–1254, June, 1998.

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Zakharkin, L.I., Zhigareva, G.G. & Balagurova, E.V. Synthesis of 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10 by cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with C6H5ZnCl catalyzed by palladium complexes. Russ Chem Bull 47, 1222–1223 (1998). https://doi.org/10.1007/BF02503502

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  • DOI: https://doi.org/10.1007/BF02503502

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