Russian Chemical Bulletin

, Volume 47, Issue 6, pp 1218–1220 | Cite as

p-(Chloro-tert-butyl)cumene hydroperoxide

  • N. N. Novitskaya
  • F. Z. Galin
  • V. V. Shereshovets
  • Yu. V. Tomilov
  • G. A. Tolstikov
Brief Communications
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Abstract

Oxidation of a mixture ofm- andp-(chloro-tert-butyl) cumenes (12:88) by molecular oxygen gives onlyp-(chloro-tert-butyl)cumene hydroperoxide in a high yield; this product can be used for the synthesis of the pyrethroid ethofenprox.

Key words

p-(chloro-ert-butyl)cumene oxidation by molecular O2 hydroperoxide pyrethroids 

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References

  1. 1.
    N. N. Mel'nikov, and N. I. Aronova,Agrokhimiya, 1987, 95.Google Scholar
  2. 2.
    V. N. Gramenitskaya, G. I. Nikishin, and A. D. Petrov,Dokl. Akad. Nauk SSSR, 1958,118, 497 [Dokl. Chem., 1958 (Engl. Transl.)].Google Scholar
  3. 3.
    W. A. Pryor, N. Ohto, and D. F. Church,J. Am. Chem. Soc., 1983,105, 3614.CrossRefGoogle Scholar
  4. 4.
    P. Clerc and S. Simon,Spectral Data for Structure Determination of Organic Compounds, Springer-Verlag, Berlin-Heidelberg-New York-Tokyo, 1983, 120.Google Scholar
  5. 5.
    B. D. Kruzhalov and B. I. Golovanenko,Sovmestnoe poluchenie fenola i atsetona [Simultaneous Preparation of Phenol and Acetone], Goskhimizdat, Moscow, 1963, p. 68 (in Russian).Google Scholar

Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • N. N. Novitskaya
    • 1
  • F. Z. Galin
    • 1
  • V. V. Shereshovets
    • 1
  • Yu. V. Tomilov
    • 2
  • G. A. Tolstikov
    • 1
  1. 1.Institute of Organic ChemistryUfa Research Center of the Russian Academy of SciencesUfaRussian Federation
  2. 2.N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of SciencesMoscowRussian Federation

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