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Chemiluminescence in the interaction of organoboron peroxides with water

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Abstract

Chemiluminescence (CL) was detected in the reactions of organoboron peroxides, intermediate products of the oxidation of 9-borabicyclo[3.3.1]nonane (1) by water. Triplet cyclooctanone emitting at λ=420±15 nm is the emitter of CL. A mechanism for the formation of the excited ketone was suggested. The interaction of water with other components of the reaction mixture (the initial boron hydride I, end products of its oxidation, and a number of intermediate radicals) are not accompanied by CL.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Academy of Sciences of the Republic of Bashkortostan, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. G. Bulgakov & B. A. Tishin

Authors
  1. R. G. Bulgakov
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  2. B. A. Tishin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1692–1695, September, 1997.

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Bulgakov, R.G., Tishin, B.A. Chemiluminescence in the interaction of organoboron peroxides with water. Russ Chem Bull 46, 1615–1617 (1997). https://doi.org/10.1007/BF02502951

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  • DOI: https://doi.org/10.1007/BF02502951

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