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Ammounium acetate as a catalyst of the condensation of sterically hindered functionalized hydroxylamines with ketones

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Ammonium acetate was found to be a catalyst of the condensation of α-hydroxylamino oximes and α-hydroxylamino alcohols with ketones. This condensation leads to sterically hindered heterocyclic hydroxylamines, which are precursors of stable nitroxides.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    V. A. Reznikov & L. B. Volodarsky

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  1. V. A. Reznikov
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  2. L. B. Volodarsky
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1654–1658, September, 1997.

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Reznikov, V.A., Volodarsky, L.B. Ammounium acetate as a catalyst of the condensation of sterically hindered functionalized hydroxylamines with ketones. Russ Chem Bull 46, 1577–1581 (1997). https://doi.org/10.1007/BF02502943

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  • DOI: https://doi.org/10.1007/BF02502943

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