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Electrocarboxylation of 1,4-dibromobut-2-ene in a CO2-DMF liquid mixture

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The possibility of synthesizing dihydromuconic acid by cathodic carboxylation of 1,4-dibromobut-2-ene in the liquid CO2-aprotic solvent system was investigated. The low yield of dihydromuconic acid in this reaction was explained by the competing reductive debromodimerization and oligomerization of 1,4-dibromobut-2-ene, which lead to the predominant formation of 1,8-dibromo-2,6-octadiene and polymeric products.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117071, Moscow, Russian Federation

    V. A. Grinberg, V. M. Mazin, E. I. Mysov & S. R. Sterlin

  2. Central Research and Development E. I. Du Pont de Nemours and Company, Inc., Experimental Station, P.O. Box 80262, 19880-0262, Wilmington, DE, USA

    T. A. Koch

Authors
  1. V. A. Grinberg
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  2. T. A. Koch
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  3. V. M. Mazin
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  4. E. I. Mysov
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  5. S. R. Sterlin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1637–1641, September, 1997.

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Grinberg, V.A., Koch, T.A., Mazin, V.M. et al. Electrocarboxylation of 1,4-dibromobut-2-ene in a CO2-DMF liquid mixture. Russ Chem Bull 46, 1560–1564 (1997). https://doi.org/10.1007/BF02502939

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  • DOI: https://doi.org/10.1007/BF02502939

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