Abstract
The action of elastic wave pulses from a rheological explosion on solid glassy polyepoxides, including those doped with Co2+ and Ni2+ complexes, leads to the generation of stable dimethylbenzyl radicals. The structures of the polyepoxides and the concentration of Co2+ and Ni2+ complexes in them have an effect on the mechanochemical yield of these radicals and on the pressure at which the rheological explosion occurs.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1622–1625, September, 1997.
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Aleksandrov, A.I., Metlenkova, I.Y., Zelenetskii, A.N. et al. Chemical processes following mechanical pulse action on polyepoxide resins doped with cobalt and nickel acetates. Russ Chem Bull 46, 1546–1548 (1997). https://doi.org/10.1007/BF02502936
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DOI: https://doi.org/10.1007/BF02502936