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1H and13C NMR spectra of polycyclic compounds

7. Stereochemical identification of a mixture of five stereoisomeric norbornadiene trimers

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

Using 2D1H and13C correlation NMR spectroscopy, all signals in the1H and13C NMR spectra of five stereoisomeric bicyclo[2.2.1]heptadiene trimers, decacyclo[9.9.1.02.10.03.8.04.6.05.9.012.20.013.18.014.16.015.19]heneicosanes, obtained by Pd-catalyzed codimerization of norbornadiene dimer with quadricyclane followed by homocyclotrimerization of the latter were assigned unambiguously. Independent stereochemical identification of the trimers was performed using data on the nuclear Overhauser effect.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis of the Bashkortostan Republic Academy of Sciences and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    L. M. Khalilov, R. I. Khusnutdinov & U. M. Dzhemilev

  2. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450045, Ufa, Russian Federation

    O. V. Shitikova & L. V. Spirikhin

Authors
  1. L. M. Khalilov
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  2. O. V. Shitikova
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  3. L. V. Spirikhin
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  4. R. I. Khusnutdinov
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  5. U. M. Dzhemilev
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Additional information

For Part 6, see Ref. 1: for Parts 1–5, see Refs. 2–6.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 63–67, January, 2000.

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Khalilov, L.M., Shitikova, O.V., Spirikhin, L.V. et al. 1H and13C NMR spectra of polycyclic compounds. Russ Chem Bull 49, 64–69 (2000). https://doi.org/10.1007/BF02499067

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  • DOI: https://doi.org/10.1007/BF02499067

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