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Russian Chemical Bulletin

, Volume 47, Issue 2, pp 310–312 | Cite as

Alkylation of β-dicarbonyl compounds with 1,2-dibromocyclohexane

  • N. S. Sadykhov
  • Sh. S. Nasibov
  • F. M. Muradova
  • R. A. Gasymov
Organic Chemistry

Abstract

Alkylation of acetylacetone, ethyl acetoacetate, and diethyl malonate with 1,2-dibromocyclohexane in the presence of K2CO3 in DMSO occurs only asC-alkylation accompanied by dehydrobromination, whereas a similar reaction of dimedone follows bothC- andO-alkylation pathways.

Key words

β-dicarbonyl compounds alkylation with 1,2-dibromocyclohexane 

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References

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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • N. S. Sadykhov
    • 1
  • Sh. S. Nasibov
    • 1
  • F. M. Muradova
    • 1
  • R. A. Gasymov
    • 1
  1. 1.M. A. Rasulzade Baku State UniversityBakuRepublic of Azerbaidzhan

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