Abstract
Under the catalytic action of palladium,o-hydroxy- oro-amino-substituted aryl iodides oxidatively add to palladium(0), insert strained or rigid olefins, and close the ring between the aliphatic carbon and theortho-functional group. This reaction occurs under mild conditions in the absence of phosphine ligands in a DMF solution and affords fused dihydrofurans or-pyrroles.
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Dipartimento di Chimica Organica e Industriale dell'Universita, Viale delle Scienze, I-43100 Parma, Italia.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 957–960, May, 1998.
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Catellani, M., Del Rio, A. Catalytic arylation of carbon-carbon double bond followed by N- or O-cyclization. Russ Chem Bull 47, 928–931 (1998). https://doi.org/10.1007/BF02498163
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DOI: https://doi.org/10.1007/BF02498163