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Organometallic ABC-triblock copolymers

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The interaction of Fe and Pd complexes with double bonds of the polybutadiene (PB) block in polystyrene-polybutadiene-poly(methyl methacrylate) block copolymers has been studied. The incorporation of Fe(CO)3 fragments into the PB bloc was found to result in an increase in its rigidity. The presence of iron or palladium complexes in the PB block affects strongly the morphology of the triblock copolymers.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    L. M. Bronstein, M. V. Seregina, I. M. Yanovskaya & P. M. Valetsky

  2. Institute of Organic Chemistry, Johannes Gutenberg Mainz University, 55099, Mainz, Germany

    U. Breiner, V. Abetz & R. Stadler

  3. BASF AG, 67056, Ludwigshafen, Germany

    U. Breiner

  4. Department of Macromolecular Chemistry II, University of Bayreuth, 95440, Bayreuth, Germany

    V. Abetz & R. Stadler

Authors
  1. L. M. Bronstein
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  2. M. V. Seregina
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  3. I. M. Yanovskaya
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  4. P. M. Valetsky
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  5. U. Breiner
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  6. V. Abetz
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  7. R. Stadler
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Additional information

Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, 55099 Mainz, Deutschland.

BASF AG, 67056 Ludwigshafen, Deutschland (current address).

Makromolekulare Chemie II, Universität Bayreuth, 95440 Bayreuth, Deutschland (current address).

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 908–912, May, 1998.

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Bronstein, L.M., Seregina, M.V., Yanovskaya, I.M. et al. Organometallic ABC-triblock copolymers. Russ Chem Bull 47, 879–883 (1998). https://doi.org/10.1007/BF02498156

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  • DOI: https://doi.org/10.1007/BF02498156

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