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Novel superelectrophilic complexes for low-temperature alkane and cycloalkane transformations

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Abstract

The results of studies on the elaboration of new superelectrophilic complexes and their use for efficient low-temperature transformations of alkanes and cycloalkanes, such as cracking, isomerization, alkylation, and single-step functionalization (acylation, carbonylation, ionic monobromination, sulfurization, thioacylation,etc.), are summarized. The activity of new aprotic organic and inorganic superacids is compared to that of known electrophilic systems, including protic superacids. The reasons for the superelectrophilic properties of new active systems are considered.

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  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    I. S. Akhrem & A. V. Orlinkov

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  1. I. S. Akhrem
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  2. A. V. Orlinkov
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This review, which was initiated by Mark Efimovich Vol'pin, is a tribute of our memory and gratitude to him.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 771–795, May, 1998.

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Akhrem, I.S., Orlinkov, A.V. Novel superelectrophilic complexes for low-temperature alkane and cycloalkane transformations. Russ Chem Bull 47, 740–764 (1998). https://doi.org/10.1007/BF02498141

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