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Russian Chemical Bulletin

, Volume 48, Issue 8, pp 1519–1525 | Cite as

Synthesis of vicinal bishydroxylamine

  • V. I. Ovcharenko
  • S. V. Fokin
  • G. V. Romanenko
  • I. V. Korobkov
  • P. Rey
Organic Chemistry

Abstract

Reduction of 2,3-dimethyl-2,3-dinitrobutane with Zn in aqueous ethanol in the presence of NH4Cl affords 2,3-bis(hydroxylamino)-2,3-dimethylbutane together with 2,3-diamino-2,3-dimethylbutane and complex Zn salts. A modified procedure was developed for the synthesis of bishydroxylamine, which involves reduction in a Zn/NH4Cl/THF−H2O system.

Key words

reduction of nitro derivatives hydroxylamine derivatives nitroxyl radicals ethylenediamine derivatives ZnII complexes X-ray diffraction analysis 

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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • V. I. Ovcharenko
    • 1
  • S. V. Fokin
    • 1
  • G. V. Romanenko
    • 1
  • I. V. Korobkov
    • 1
  • P. Rey
    • 2
  1. 1.International Tomography CenterSiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation
  2. 2.C.E.A-Département de Recherche Fondamentale sur la Matiére Condensée, Service de Chimie Inorganique et BiologiqueLaboratoire de Chimie de Coordination (URA CNRS 1194)GrenobleFrance

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