Abstract
Acid-base properties of bulk 12-tungstophosphoric heteropolyacid (HPWA) and HPWA supported on alumina and fluorinated alumina were studied by DRIFT spectroscopy using adsorption of probe molecules. Catalytic properties of Pt-containing catalysts carried by these supports were studied inn-pentane isomerization. It was shown that the Pt/HPWA/Al2O3 system is almost inactive in isomerization as a result of the interaction of HPWA with basic sites of the alumina support. On the contrary, the presence of acidic sites in fluorinated alumina prevents HPWA destruction and favors the uniform distribution of HPWA on the support surface. As a result, enhancement of the activity and selectivity of the Pt/HPWA/Al2O3-F catalyst inn-pentane isomerization is observed.
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References
M. -T. Tran, N. S. Gnep, G. Szabo, and M. Guisnet,Appl. Catal. A: General, 1998,170 49.
J. -K. Lee and H. -K. Rhee,Catal. Today, 1997,38, 235.
A. Corma,Chem. Rev., 1995,95, 559.
X. Song and A. Sayari,Catal. Rev.—Sci. Eng., 1996,38, 329.
V. Adeeva, H. Y. Liu, B. Q. Xu, and W. M. H. Sachtler,Topics in Catal., 1998,6, 61.
A. K. Sinha and S. Sivasanker,Catal. Today, 1999,49, 293.
T. Okuhara, N. Mizuno, and M. Misono,Adv. Catal., 1996,41, 113.
N. Mizuno and M. Misono,Chem. Rev., 1998,98, 199.
I. V. Kozhevnikov,Chem. Rev., 1998,98, 171.
I. V. Kozhevnikov,Catal. Rev., Sci. Eng., 1995,37, 311.
W. -C. Cheng and N. P. Putra,J. Catal., 1988,109, 163.
H. Ehwald, W. Fiebig, H. -G. Jerschkewitz, G. Lischke, B. Parlitz, P. Reich, and G. Öhlmann,Appl. Catal., 1987,34, 23.
G. Mestl and H. Knözinger, inHandbook of Heterogeneous Catalysis, Eds. G. Ertl, H. Knözinger, and J. Weitkamp. Wiley VCH, New York, 1997, 539.
E. A. Paukshtis, R. I. Soltanov, E. N. Yurchenko, and K. Jiratova,Coll. Czech. Chem. Commun., 1982,47, 2044.
E. B. Uvarova, L. M. Kustov, and V. B. Kazansky,Stud. Surf. Sci. Catal., 1995,94, 254.
L. M. Sverdlov, M. A. Kovner, and E. P. Krainov,Kolebatel'nye spektry mnogoatomnykh molekul [Vibrational Spectra of Polyatomic Molecules], Nauka, Moscow, 1970 (in Russian).
E. A. Paukshtis, L. G. Karakchiev, and N. S. Kotsarenko,React. Kinet. Catal. Lett., 1979,12, 315.
A. V. Ivanov and L. M. Kustov,Izv. Akad. Nauk, Ser. Khim., 2000 38 [Russ. Chem. Bull., Int. Ed., 2000,49, 39 (Engl. Transl.)].
A. V. Ivanov and L. M. Kustov,Abstr. of Papers, EUROPACAT-4, 1999, Rimini, Italy, 167.
L. M. Kustov, V. B. Kazansky, F. Figueras, and D. Tichit,J. Catal., 1994,150, 143.
J. A. Martens and P. A. Jacobs, inHandbook of Heterogenous Catalysis, Eds. G. Ertl, H. Knözinger, and J. Weitkamp, Wiley VCH, New York, 1997, 1137.
B. A. Lerner, B. T. Carvill, and W. M. H. Sachtler,Catal. Lett., 1993,18, 227.
S. Rezgui and B. C. Gates,Catal. Lett., 1996,37, 5.
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1744–1750, October, 2000.
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Ivanov, A.V., Vasina, T.V., Masloboishchikova, O.V. et al. n-Alkane isomerization on heteropolyacids. Russ Chem Bull 49, 1726–1731 (2000). https://doi.org/10.1007/BF02496342
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DOI: https://doi.org/10.1007/BF02496342