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Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidin-1-oxyl

  • Physical Chemistry
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Abstract

The complex formation of ClO2 with 2,2,6,6-tetramethylpiperidin-1-oxyl (TMPO) in acetone, acetonitrile,n-heptane, diethyl ether, carbon tetrachloride, and toluene was studied spectrophotometrically at −20 to +20 °C. The thermodynamic parameters of complex formation were determined at 20 °C. The transformation of the complex into the oxoammonium salt TMPO+ClO −2 was found.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    I. M. Ganiev & V. V. Shereshovets

  2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    I. A. Grigor'ev & G. A. Tolstikov

Authors
  1. I. M. Ganiev
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  2. V. V. Shereshovets
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  3. I. A. Grigor'ev
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  4. G. A. Tolstikov
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Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1703–1706, October, 2000.

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Ganiev, I.M., Shereshovets, V.V., Grigor'ev, I.A. et al. Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidin-1-oxyl. Russ Chem Bull 49, 1687–1690 (2000). https://doi.org/10.1007/BF02496334

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  • DOI: https://doi.org/10.1007/BF02496334

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