Abstract
Addition of alcohols to bis(chloromethyl)phosphinoyl isocyanate, as well as the reaction of bis(chloromethyl)phosphinoyl chloride with urethanes or their silylated derivatives, gave the corresponding phosphorylated carbamates which undergo cyclization into 1,3,4-oxazaphospholines under the action of Et3N.
This is a preview of subscription content, log in via an institution to check access.
References
R. M. Kamalov, G. S. Stepanov, L. F. Chertanova, A. A. Gazikasheva, M. A. Pudovik, and A. N. Pudovik,Heteroatom. Chem., 1992,3, 115.
R. M. Kamalov, G. S. Stepanov, I. A. Litvinov, and M. A. Pudovik,Heteroatom. Chem., 1994,5, 469.
M. A. Pudovik, L. K. Kibardina, R. M. Kamalov, R. Kh. Al'myanova, and A. N. Pudovik.Izv. Akad. Nauk, Ser. Khim., 1996, 1857 [Russ. Chem. Bull., 1996,45, 1769 (Engl. Transl.)].
R. M. Kamalov, R. Kh. Al'myanova, and M. A. Pudovik,Zh. Obshch. Khim., 1994,64, 1781 [Russ. J. Gen. Chem., 1994,64 (Engl. Transl.)].
R. M. Kamalov, R. Kh. Al'myanova, and M. A. Pudovik,Phosphorus, Sulfur and Silicon, 1996,111, 153.
M. A. Pudovik, R. M. Kamalov, and R. Kh. Al'myanova,Zh. Obshch. Khim. 1996,66, 364 [Russ. J. Gen. Chem., 1996,66 (Engl. Transl.)].
G. I. Dergach and N. P. Smetankina,Zh. Obshch. Khim., 1964,34, 3613 [J. Gen. Chem. USSR, 1964,34 (Engl. Transl.)].
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 810–811, April, 1999.
Rights and permissions
About this article
Cite this article
Pudovik, M.A., Saakyan, G.M., Khairullin, V.K. et al. Synthesis of 1,3,4-oxazaphospholines based on phosphorylated carbamates. Russ Chem Bull 48, 806–807 (1999). https://doi.org/10.1007/BF02496276
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02496276