Advertisement

Russian Chemical Bulletin

, Volume 48, Issue 4, pp 806–807 | Cite as

Synthesis of 1,3,4-oxazaphospholines based on phosphorylated carbamates

  • M. A. Pudovik
  • G. M. Saakyan
  • V. K. Khairullin
  • N. A. Khailova
  • A. N. Pudovik
Brief Communications

Abstract

Addition of alcohols to bis(chloromethyl)phosphinoyl isocyanate, as well as the reaction of bis(chloromethyl)phosphinoyl chloride with urethanes or their silylated derivatives, gave the corresponding phosphorylated carbamates which undergo cyclization into 1,3,4-oxazaphospholines under the action of Et3N.

Key words

bis(chloromethyl)phosphinoyl chloride(isocyanate) phosphorylated carbamates heterocyclization 1,3,4-oxazaphospholines 

References

  1. 1.
    R. M. Kamalov, G. S. Stepanov, L. F. Chertanova, A. A. Gazikasheva, M. A. Pudovik, and A. N. Pudovik,Heteroatom. Chem., 1992,3, 115.CrossRefGoogle Scholar
  2. 2.
    R. M. Kamalov, G. S. Stepanov, I. A. Litvinov, and M. A. Pudovik,Heteroatom. Chem., 1994,5, 469.CrossRefGoogle Scholar
  3. 3.
    M. A. Pudovik, L. K. Kibardina, R. M. Kamalov, R. Kh. Al'myanova, and A. N. Pudovik.Izv. Akad. Nauk, Ser. Khim., 1996, 1857 [Russ. Chem. Bull., 1996,45, 1769 (Engl. Transl.)].Google Scholar
  4. 4.
    R. M. Kamalov, R. Kh. Al'myanova, and M. A. Pudovik,Zh. Obshch. Khim., 1994,64, 1781 [Russ. J. Gen. Chem., 1994,64 (Engl. Transl.)].Google Scholar
  5. 5.
    R. M. Kamalov, R. Kh. Al'myanova, and M. A. Pudovik,Phosphorus, Sulfur and Silicon, 1996,111, 153.Google Scholar
  6. 6.
    M. A. Pudovik, R. M. Kamalov, and R. Kh. Al'myanova,Zh. Obshch. Khim. 1996,66, 364 [Russ. J. Gen. Chem., 1996,66 (Engl. Transl.)].Google Scholar
  7. 7.
    G. I. Dergach and N. P. Smetankina,Zh. Obshch. Khim., 1964,34, 3613 [J. Gen. Chem. USSR, 1964,34 (Engl. Transl.)].Google Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • M. A. Pudovik
    • 1
  • G. M. Saakyan
    • 1
  • V. K. Khairullin
    • 1
  • N. A. Khailova
    • 1
  • A. N. Pudovik
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan' Scientific Center of the Russian Academy of SciencesKazan'Russian Federation

Personalised recommendations