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Russian Chemical Bulletin

, Volume 48, Issue 4, pp 801–803 | Cite as

Regeneration of the Ru(bipy)3Cl2 excitation under chemiluminescence activation in the reaction of diphenylmethane autooxidation in an alkaline medium

  • V. P. Kazakov
  • V. N. Yakovlev
  • G. Ya. Maistrenko
  • A. D. Karavaev
  • A. I. Voloshin
Brief Communications

Abstract

The effect of the Ru(bipy)3Cl2 [RuII] complex on chemiluminescence in the autooxidation of diphenylmethane in the presence of BuIOK was studied. The luminescence increases due to the participation of an activator in the redox processes. The excitation of the RII complex occurs in the stage of oxidation by the superoxide anion of the RuI complex formed by the one-electron reduction of the initial RuII by anions.

Key words

chemiluminescence Ru(bipy)3Cl2 diphenylmethane autooxidation electron-transfer 

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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • V. P. Kazakov
    • 1
  • V. N. Yakovlev
    • 1
  • G. Ya. Maistrenko
    • 1
  • A. D. Karavaev
    • 1
  • A. I. Voloshin
    • 1
  1. 1.Institute of Organic ChemistryUfa Research Center of the Russian Academy of SciencesUfaRussian Federation

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