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Russian Chemical Bulletin

, Volume 48, Issue 4, pp 794–795 | Cite as

Synthesis of the first unsymmetrical 34-electron cationic cobalt-nickel triple-decker complex with a central cyclopentadienyl ligand [(η-C6Me6)Co(μ-η:η-C5H5)Ni(η-C5H5)]PF6

  • A. R. Kudinov
  • D. V. Muratov
  • P. V. Petrovskii
  • M. I. Rybinskaya
Organometallic Chemistry

Abstract

The first unsymmetrical 34-electron cationic cobalt-nickel triple-decker complex with a central cyclopentadienyl ligand [(η-C6Me6)Co(μ-η:η-C5H5)Ni(η-C5)PF6 was prepared by the reaction of [(η-C6Me6)2Co]PF6 with nickelocene.

Key words

triple-decker complexes sandwich compounds cobalt complexes nickel complexes 

References

  1. 1.
    H. Werner and A. Salzer,Synth. Inorg. Met.-Org. Chem., 1972,2, 239.Google Scholar
  2. 2.
    A. Salzer and H. Werner,Angew. Chem., Int. Ed. Engl., 1972,11, 930.CrossRefGoogle Scholar
  3. 3.
    E. Dubler, M. Textor, H.-R. Oswald, and A. Salzer,Angew. Chem., Int. Ed. Engl., 1974,13, 135.CrossRefGoogle Scholar
  4. 4.
    E. Dubler, M. Textor, H.-R. Oswald, and G. B. Jameson,Acta Crystallogr., 1983,B39, 607.Google Scholar
  5. 5.
    J. Edwin and W. E. Geiger,Organometallics, 1984,3, 1910.CrossRefGoogle Scholar
  6. 6.
    E. O. Fischer and H. H. Lindner,J. Organomet. Chem., 1964,1, 307.CrossRefGoogle Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • A. R. Kudinov
    • 1
  • D. V. Muratov
    • 1
  • P. V. Petrovskii
    • 1
  • M. I. Rybinskaya
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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