Advertisement

Russian Chemical Bulletin

, Volume 48, Issue 4, pp 785–789 | Cite as

Chemical and electrochemical oxidation of permethylmetallocenecarbaldehydes and the related μ-acyl Os3-clusters

  • L. N. Kiseleva
  • A. Z. Kreindlin
  • L. I. Denisovich
  • M. G. Peterleitner
  • Z. S. Klemenkova
  • P. V. Petrovskii
  • M. I. Rybinskaya
Organometallic Chemistry
  • 26 Downloads

Abstract

Oxidation of nonamethylmetallocenecarbaldehydes C5Me5MC5Me4CHO (M=Ru or Os) and the related μ-acyl clusters C5Me5MC5Me4COOs3(CO)10H with silver salts afforded η6-metallonium cations, whose structures and compositions were confirmed by the data of elemental analysis and1H,19F, and13C NMR and IR spectroscopy. The results of studies by cyclic voltammetry demonstrated that oxidation of the compounds under study proceeded through 17-electron radical-cationic intermediates and that the μ-acyl Os3-cluster fragment is a weaker electron-withdrawing group than the CHO group.

Key words

μ-acyl clusters permethylmetallocenecarbaldehydes ruthenium osmium IR spectroscopy 1H NMR spectroscopy 19F NMR spectroscopy 13C NMR spectroscopy oxidation cyclic voltammetry η6-metallonium cations 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    N. V. Kruglova, A. Z. Kreindlin, P. V. Petrovskii, and M. I. Rybinskaya,Izv. Akad. Nauk, Ser. Khim., 1996, 2979 [Russ. Chem. Bull., 1996,45, 2830 (Engl. Transl.)].Google Scholar
  2. 2.
    M. I. Rybinskaya, A. Z. Kreindlin, and S. S. Fadeeva,J. Organomet. Chem., 1988,358, 363.CrossRefGoogle Scholar
  3. 3.
    L. I. Denisovich, M. G. Peterleitner, D. N. Kravtsov, A. Z. Kreindlin, S. S. Fadeeva, and M. I. Rybinskaya,Metalloorg. Khim., 1988,1, 301 [Organomet. Chem. USSR, 1988,1 (Engl. Transl.)].Google Scholar
  4. 4.
    S. V. Kukharenko, V. V. Strelets, L. I. Denisovich, M. G. Peterleitner, A. Z. Kreindlin, A. R. Kudinov, and M. I. Rybinskaya,Izv. Akad. Nauk, Ser. Khim., 1995, 2394 [Russ. Chem. Bull., 1995,44, 2289 (Engl. Transl.)].Google Scholar
  5. 5.
    S. V. Kukharenko, V. V. Strelets, A. R. Kudinov, A. Z. Kreindlin, M. G. Peterleitner, L. I. Denisovich, and M. I. Rybinskaya,J. Organomet. Chem., 1996,519, 1.CrossRefGoogle Scholar
  6. 6.
    A. Z. Kreindlin, P. V. Petrovskii, I. G. Barakovskaya, L. M. Epshtein, E. S. Shubina, and M. I. Rybinskaya,Izv. Akad. Nauk, Ser. Khim., 1999, 180 [Russ. Chem. Bull., 1999,48, 179 (Engl. Transl.)].Google Scholar
  7. 7.
    I. A. Garbuzova, A. R. Kudinov, M. I. Rybinskaya, and B. V. Lokshin,Metalloorg. Khim., 1989,2, 922 [Organomet. Chem. USSR, 1989,2 (Engl. Transl.)].Google Scholar
  8. 8.
    A. Z. Kreindlin, E. I. Fedin, P. V. Petrovskii, M. I. Rybinskaya, R. M. Minyaev, and R. Hoffmann,Organometallics, 1991,10, 1206.CrossRefGoogle Scholar
  9. 9.
    M. I. Rybinskaya, and A. Z. Kreindlin, P. V. Petrovskii, R. M. Minyaev, and R. Hoffmann,Organometallics, 1994,13, 3903.CrossRefGoogle Scholar
  10. 10.
    A. Z. Kreindlin, P. V. Petrovskii, M. I. Rybinskaya, A. I. Yanovsky, and Yu. T. Struchkov,J. Organomet. Chem., 1987,319, 229.CrossRefGoogle Scholar
  11. 11.
    A. Z. Kreindlin, P. V. Petrovskii, and M. I. Rybinskaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 1620 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987,36, 1489 (Engl. Transl.)].Google Scholar
  12. 12.
    A. J. Arce, P. A. Bates, S. P. Best, R. J. H. Clark, and A. J. Deeming,J. Chem. Soc., Chem. Commun., 1988, 478.Google Scholar

Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • L. N. Kiseleva
    • 1
  • A. Z. Kreindlin
    • 1
  • L. I. Denisovich
    • 1
  • M. G. Peterleitner
    • 1
  • Z. S. Klemenkova
    • 1
  • P. V. Petrovskii
    • 1
  • M. I. Rybinskaya
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

Personalised recommendations