Russian Chemical Bulletin

, Volume 48, Issue 4, pp 774–780 | Cite as

Synthesis and transformations of metallocycles

19. Synthesis of 3-alkylalumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes on Zr-containing complex catalysts
  • A. G. Ibragimov
  • L. O. Khafizova
  • L. G. Yakovleva
  • E. V. Nikitina
  • K. G. Satenov
  • L. M. Khalilov
  • U. M. Dzhemilev
Organometallic Chemistry

Abstract

A regioselective method for the synthesis of 3-alkylalumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes by the reactions of α-olefins with EtAlCl2, ROAlCl2, R2NAlCl2, or Et2AlCl and the Mg−ClCH2CH2Cl−Cp2ZrCl2 (ZrCl4) system was developed.

Key words

organoaluminum compounds zirconium-containing catalysts cycloalumination olefins magnesium alkyl-, alkoxy-, and dialkylaminodihaloalanes 

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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • A. G. Ibragimov
    • 1
  • L. O. Khafizova
    • 1
  • L. G. Yakovleva
    • 1
  • E. V. Nikitina
    • 1
  • K. G. Satenov
    • 1
  • L. M. Khalilov
    • 1
  • U. M. Dzhemilev
    • 1
  1. 1.Institute of Petrochemistry and CatalysisAcademy of Sciences of the Republic of Bashkortostan and Ufa Research Center of the Russian Academy of SciencesUfaRussian Federation

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