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Thiocarbamoylation of amine-containing compounds

2. The reaction of tetramethylthiuram disulfide with 5-amino-2-mercaptobenzooxazole

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The reaction of 5-amino-2-mercaptobenzooxazole with tetramethylthiuram disulfide affordedN,N-dimethylthioureido-2-mercaptobenzooxazole, which was converted into 5-isothiocyanato-2-mercaptobenzooxazole under the action of AcCl, Ac2O, or HCl. Based on the latter compound, 4-(2-mercaptobenzooxazol-5-yl)thiosemicarbazide was synthesized, whose reactions with aldehydes and ketones yielded the corresponding thiosemicarbazones.

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References

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    Luu Van Boi

  2. Department of Organic Chemistry, University of Moldova, 60 ul. A. Matveevichi, 277009, Kishinev, Moldova

    A. Zadorozhnyi & N. Barba

Authors
  1. Luu Van Boi
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  2. A. Zadorozhnyi
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  3. N. Barba
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Additional information

For Part 1, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 771–774, April, 1999.

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Boi, L.V., Zadorozhnyi, A. & Barba, N. Thiocarbamoylation of amine-containing compounds. Russ Chem Bull 48, 767–770 (1999). https://doi.org/10.1007/BF02496266

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  • DOI: https://doi.org/10.1007/BF02496266

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