Russian Chemical Bulletin

, Volume 48, Issue 4, pp 743–745 | Cite as

Reactions of α-chloro β-oxo aldehydes with CH-acid anions

  • F. I. Guseinov
Organic Chemistry


The reactions of α-chloro and α,α-dichloro β-oxo aldehydes with carbanions are accompanied by the cleavage of the carbon-carbon bond in the chloro aldehydes and result in formylation of CH-acids. These electrophiles react with carbanions, which are generatedin situ from CH-acids in the presence of AcONa in aprotic solvents, to form polyfunctional hydroxy compounds.

Key words

α-chloro β-oxo aldehydes carbanions CH-acids 


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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • F. I. Guseinov
    • 1
  1. 1.Kazan' State Technological UniversityKazan'Russian Federation

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