Russian Chemical Bulletin

, Volume 48, Issue 4, pp 726–729 | Cite as

Gas chromatographic indicator of the ability of five- and six-membered heterocyclic nitrogen-containing compounds for self-association in pure liquids

  • R. V. Golovnya
  • T. E. Kuz'menko
  • I. L. Zhuravleva
Physical Chemistry

Abstract

The retention indices of five- and six-membered nitrogen-containing heterocyclic compounds (pyrrole, pyrazole, imidazole, 1,2,4-triazole, pyridine, pyridazine, pyrimidine, pyrazine, 1,3,5-triazine, isoxazole, and oxazole) were determined on a capillary column with the OV-101 nonpolar stationary phase. The difference between the experimentally determined boiling point of the sorbate and that calculated from GC data (δT b.p.) was proposed as a gas chromatographic indicator sensitive to the ability of substances to form self-associates in pure liquids.

Key words

capillary gas-liquid chromatography five- and six-membered heterocyclic nitrogen-containing compounds retention indices self-association of sorbate gas chromatographic indicator of self-association 

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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • R. V. Golovnya
    • 1
  • T. E. Kuz'menko
    • 1
  • I. L. Zhuravleva
    • 1
  1. 1.N. M. Emanuel' Institute of Biochemical PhysicsRussian Academy of SciencesMoscowRussian Federation

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