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Russian Chemical Bulletin

, Volume 46, Issue 6, pp 1167–1170 | Cite as

19F NMR studies of the comparative electronegativity of the Ph3E groups (E=C, Si, Ge, Sn, or Pb) in Ph3E derivatives of tris(4-fluorophenyl)stannanethiol

  • D. N. Kravtsov
  • A. S. Peregudov
  • A. I. Krylova
  • Yu. Yu. Gorelikova
Organometallic Chemistry

Abstract

Compounds (4-FC6H4)3SnSEPh3 (E=C, Si, Ge, Sn, or Pb) were synthesized or generated in solution. The data on the comparative electronegativity of the Ph3E groups were obtained from the results of19F NMR spectroscopy. It was established that, except for E=C, the electronegativity changes in parallel with the absolute electronegativity of the central atom. Possible reasons for the deviation observed are discussed.

Key words

electronegativity group electronegativity carbon, silicon, germanium, tin, lead 19F NMR spectra 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • D. N. Kravtsov
    • 1
  • A. S. Peregudov
    • 1
  • A. I. Krylova
    • 1
  • Yu. Yu. Gorelikova
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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