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Cationic arenerhodacarboranes [(ν-arene) Rh(ν-7,8-Me2-7,8-C2B9H9)]BF4

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

A new procedure was developed for the synthesis of (η3-C8H13)Rh(η-7,8-C2B9H9) (1). This method involves the interaction of [codRhCl]2 with Cs[7,8-Me2-7,8-C2B9H10] in CH2Cl2. The reactions of compound1 with arenes in trifluoroacetic acid afforded, the previously unknown cationic arenerhodacarboranes [(ν-arene) Rh(ν-7,8-Me2-7,8-C2B9H9)]BF4 in high yields.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. R. Kudinov, R. T. Bogoudinov, P. V. Petrovskii & M. I. Rybinskaya

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  1. A. R. Kudinov
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  2. R. T. Bogoudinov
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  3. P. V. Petrovskii
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  4. M. I. Rybinskaya
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 592–594, March, 1999.

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Kudinov, A.R., Bogoudinov, R.T., Petrovskii, P.V. et al. Cationic arenerhodacarboranes [(ν-arene) Rh(ν-7,8-Me2-7,8-C2B9H9)]BF4 . Russ Chem Bull 48, 586–588 (1999). https://doi.org/10.1007/BF02496185

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  • DOI: https://doi.org/10.1007/BF02496185

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