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Oxidative dehydrogenation of diaminomaleonitrile coordinated to the nickel and platinum atoms

Synthesis and the structure of M[HNC(CN)C(CN)NH]2 (M=Ni or Pt)

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reactions of diaminomaleonitrile H2NC(CN)=C(CN)NH2 (1) with the nine-nuclear carboxylate nickel(II) complex Ni9(HOOCCMe3)4(μ4-OH)3(μn-OOCCMe3)12 (under an inert atmosphere or in air) and with K2[PtX4] (in air) afforded the bis-chelate mononuclear complexes M[HNC(CN)C(CN)NH]2 (M=Ni (2) and Pt (3), respectively). The structural features of compounds 1, 2, and 3, which were determined by X-ray diffraction analysis, are discussed.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp, 117907, Moscow, Russian Federation

    A. A. Sidorov, I. G. Fomina, S. E. Nefedov, I. L. Eremenko & I. I. Moiseev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    V. V. Nesterov

Authors
  1. A. A. Sidorov
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  2. I. G. Fomina
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  3. V. V. Nesterov
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  4. S. E. Nefedov
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  5. I. L. Eremenko
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  6. I. I. Moiseev
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 578–582, March, 1999.

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Sidorov, A.A., Fomina, I.G., Nesterov, V.V. et al. Oxidative dehydrogenation of diaminomaleonitrile coordinated to the nickel and platinum atoms. Russ Chem Bull 48, 573–577 (1999). https://doi.org/10.1007/BF02496182

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  • DOI: https://doi.org/10.1007/BF02496182

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