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Nitrosation of arenes with nitrosonium ethyl sulfate

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Nitrosonium ethyl sulfate reacts withO-alkylphenols andN,N-dialkylanilines to give the corresponding 4-nitrosoarenes. The reaction is not accompanied by side processes characteristic of common nitrosating agents. Diazotization of primary aromatic amines with nitrosonium ethyl sulfate yields stable diazonium salts, which are promising reagents for organic synthesis.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    N. V. Zyk, E. E. Nesterov, A. N. Khlobystov & N. S. Zefirov

Authors
  1. N. V. Zyk
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  2. E. E. Nesterov
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  3. A. N. Khlobystov
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  4. N. S. Zefirov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 510–513, March, 1999.

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Zyk, N.V., Nesterov, E.E., Khlobystov, A.N. et al. Nitrosation of arenes with nitrosonium ethyl sulfate. Russ Chem Bull 48, 506–509 (1999). https://doi.org/10.1007/BF02496170

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  • DOI: https://doi.org/10.1007/BF02496170

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