Russian Chemical Bulletin

, Volume 48, Issue 3, pp 484–487 | Cite as

X-ray photoelectron spectra and structure of 2-(2-phenylhydrazono) acetoacetanilide

  • T. M. Ivanova
  • B. E. Zaitsev
  • R. V. Linko
  • M. A. Ryabov
  • K. M. Dyumaev
Physical Chemistry
  • 34 Downloads

Abstract

2-(2-Phenylhydrazono)acetoacetanilide, itsN-methyl derivatives, and model compounds were studied by X-ray photoelectron spectroscopy. The chemical shifts were obtained from the13C NMR spectra. A correlation between the calculated charges, the binding energies on N atoms, and the13C NMR chemical shifts was found. The analysis of the XPS data and the13C NMR chemical shifts led to the conclusion that crystalline 2-(2-phenylhydrazono)acetoacetanilide exists mainly in the oxo hydrazone form.

Key words

2′-(2-phenylhydrazono)acetoacetanilide X-ray photoelectron and13C NMR spectra binding energies chemical shifts 

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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • T. M. Ivanova
    • 1
  • B. E. Zaitsev
    • 1
  • R. V. Linko
    • 1
  • M. A. Ryabov
    • 1
  • K. M. Dyumaev
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation

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