Abstract
Electronic absorption spectra of complexes of C60 and C70 fullerenes with donors, tetrathiafulvalene and pyranylidene derivatives, were studied in solutions and in the solid state. Charge transfer bands were found in the 680–1300 nm range. The charge transfer energies (hv ct) for the C60 and C70 complexes in solutions are close and almost independent of the solvent polarity. For the C60 complexes in the solid state, the dependence ofhv ct on the ionization potential (IP) of donors was found to behv ct=0.82IP–3.93 eV. In the C60 complexes in the solid state, thehv ct values are 0.15–0.20 eV lower than those in the solution. The linear dependences ofhv ct onIP of donors for the C60 complexes lie 0.6–0.7 eV higher than those in the complexes with tetracyanoethylene (TCNE). This is associated with lower values of the electron affinity of C60 and the energy of the electrostatic interaction in the fullerene complexes as compared to those of the TCNE complexes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
L.-S. Wang, J. Conceicao, C. Jim, and R. E. Smalley,Chem. Phys. Lett., 1991,182, 5.
C. Brink, L. H. Anderson, P. Hvelplund, D. Mathur, and J. D. Voldstard,Chem. Phys. Lett., 1995,233, 52.
R. C. Haddon, A. F. Hebard, M. J. Rosseinsky, D. W. Murphy, S. J. Duclos, K. B. Lyons, B. Miller, J. M. Rasamilia, R. M. Fleming, A. R. Kortan, S. H. Glarum, A. V. Makhija, A. J. Muller, R. H. Eick, S. M. Zehurak, R. Tycko, G. Dabbagh, and F. A. Thiel,Nature, 1991,350, 320.
P. W. Stephens, D. Cox, J. W. Lauher, L. Mihaly, J. B. Wiley, P.-M. Allemand, A. Hirsch, K. Holczer, Q. Li, J. D. Thompson, and F. Wudl,Nature (London), 1992,355, 331.
M. Ricco, M. Bisbiglia, R. De Renzi, and F. Bolzoni,Solid State Commun., 1997,101, 413.
G. Saito, T. Teramoto, A. Otsuka, Y. Sugita, T. Ban, M. Kusunoki, and K. I. Sakaguchi,Synth. Met., 1994,64, 359.
D. V. Konarev, E. F. Valeev, Yu. L. Slovokhotov, Yu. M. Shul'ga, O. S. Roschupkina, and R. N. Lyubovskaya,Synth. Met., 1997,88, 85.
P. Wang, W. Lee, I. Scherbakova, M. P. Kava, and R. M. Metzger,Synth. Mer., 1994,64, 319.
J. D. Crane, P. B. Hitchcock, H. W. Kroto, R. Taylor, and D. R. M. Walton,J. Chem. Soc., Chem. Commun., 1992, 1764.
A. Izuoka, T. Tachikawa, T. Sugawara, Y. Suzuki, M. Konno, Y. Saito, and H. Shinohara,J. Chem. Soc. Chem. Commun., 1992, 1472.
D. V. Konarev, Y. V. Zubavichus, Yu. L. Slovokhotov, Yu. M. Shul'ga, V. N. Semkin, N. V. Drichko, and R. N. Lyubovskaya,Synth. Met., 1998,92, 1.
J. Llacay, J. Tarres, J. Veciana, and C. Rovira,Synth. Met., 1995,70, 1453.
D. V. Konarev, Yu. M. Shul'ga, O. S. Roschupkina, and R. N. Lyubovskaya,J. Phys. Chem. Solids, 1997,58, 1869.
A. Izuoka, T. Tachikawa, T. Sugawara, Y. Saito, and H. Shinohara,Chem. Lett., 1992, 1049.
D. V. Konarev, O. S. Roschupkina, M. G. Kaplunov, Yu. M. Shul'ga, E. I. Yudanova, and R. N. Lyubovskaya,Molecular Materials, 1996,8, 83.
D. V. Konarev, V. N. Semkin, R. N. Lyubovskaya, and A. Graja,Synth. Met., 1997,88, 225.
V. A. Nadtochenko, N. N. Denisov, and P. P. Levin,Izv. Akad. Nauk, Ser. Khim., 1995, 1078 [Russ. Chem. Bull., 1995,44, 1038 (Engl. Transl.)].
S. P. Sibley, R. L. Campbell, and H. B. Silber,J. Phys. Chem., 1995,99, 5274.
S. P. Sibley, Y. T. Nguyen, R. L. Campbell, and H. B. Silber,Spectrochim. Acta, A, 1997,53, 679.
R. D. Scurlock, and P. R. Ogilby,J. Photochemistry and Photobiology, A: Chemistry, 1995,91, 21.
L. J. Andrews and R. M. Keefer,Molecular Complexes in Organic Chemistry, Holden-Day Inc., San Francisco-London-Amsterdam, 1964.
H. Kuruda, M. Kobayashi, M. Kobayashi, and S. Takemoto,J. Chem. Phys., 1962,36, 457.
V. E. Kampar, Z. P. Bruvers, and R. B. Kampare,Tez. dokl. V Vsesoyuzn. soveshch. po KPZ i ion-radikal'nym solyam [Proc. V All-Union Meeting on CTC and Radical Ion Salts], Chernogolovka, IKhF AN, 1981, 43 (in Russian).
N. S. Sariciftci, L. Smilovoch, A. J. Heeger, and F. Wudl,Science, 1992,258, 1474.
B. Zh. Narymbetov, S. S. Khasanov, L. V. Zorina, L. P. Rozenberg, R. P. Shibaeva, D. V. Konarev, and R. N. Lyubovskaya,Kristallografiya, 1997,58, 851 [Russ. J. Crystallogr., 1997,58, (Engl. Transl.)].
V. E. Kampar, D. V. Bite, L. F. Sukhodub, and O. A. Neiland,Zh. Org. Khim., 1977,48, 647 [J. Org. Chem. USSR, 1977,48 (Engl. Tranl.)].
D. V. Konarev, N. V. Drichko, V. N. Semkin, Yu. M. Shul'ga, A. Graja, and R. N. Lyubovskaya,Electronic Properties of Novel Materials, Eds. H. Kuzmany, J. Fink, and J. Roth, 1998, 357.
D. V. Konarev, V. N. Semkin, A. Graja, and R. N. Lyubovskaya,J. Mol. Structure, 1998,450, 11.
D. L. Lichenberger, R. L. Johnston, K. Hinkelmann, T. Suzuki, and F. Wudl,J. Am. Chem. Soc., 1990,112, 3302.
H. Spanget-Larsen, R. Gleiter, and K. Hunig,Chem. Phys. Lett., 1976,37, 29.
N. Sato, K. Seki, and H. Inokuchi,J. Chem. Soc., Faraday Trans. 2, 1981,77, 1621.
Yu. M. Shul'ga, R. N. Lyubovskaya, and D. V. Konarev,Phys. Low-Dim. Struct., 1997,1/2, 103.
R. Foster,Organic Charge Transfer Complexes, Academic Press, London, 1969.
E. C. M. Chen and W. E. Wentworth,J. Chem. Phys., 1975,63, 3183.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 478–483, March, 1999.
Rights and permissions
About this article
Cite this article
Konarev, D.V., Lyubovskaya, R.N., Drichko, N.V. et al. Charge transfer in complexes of C60 and C70 in solutions and solid state. Russ Chem Bull 48, 474–479 (1999). https://doi.org/10.1007/BF02496164
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02496164