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Trimethylacetate nickel complexes

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Abstract

The present review is devoted to the chemistry of trimethylacetate NiII complexes with various nitrogen-containing ligands. Pathways of formation of complexes containing the Ni2(μ-OH2)(μ-OOCCMe3)2 and Ni2(μ-OOCCMe3)4 fragments are discussed. Pathways of degradation of the nine-nuclear complex Ni9(HOOCCMe3)4(μ4-OH)3(μ3-OH)3)3(μ4-OOCCMe3)12 under the action of primary amines (aniline or propargylamine) as well as the process of dehydration ofN-phenyl-o-phenylenediamine up to the bischelate mononuclear complex [1,2-(NH)(NPh)C6H4]2Ni are demonstrated.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    I. L. Eremenko, S. E. Nefedov, A. A. Sidorov & I. I. Moiseev

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  1. I. L. Eremenko
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  2. S. E. Nefedov
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  3. A. A. Sidorov
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  4. I. I. Moiseev
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 409–419, March, 1999.

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Eremenko, I.L., Nefedov, S.E., Sidorov, A.A. et al. Trimethylacetate nickel complexes. Russ Chem Bull 48, 405–416 (1999). https://doi.org/10.1007/BF02496153

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