Abstract
A general method for the preparation of nitrates by treatment of alcohols with nitryl fluoride (FNO2) in MeCN in the presence of KF has been developed.
References
V. I. Metelitsa and A. B. Davydov,Preparaty nitratov v kardiologii [Nitrate Preparations in Cardiology], Meditsina, Moscow, 1989 (in Russian).
T. N. Montgomery,J. Am. Chem. Soc., 1934,56, 419.
B. M. L. Wolfrom and A. Rosenthal,J. Am. Chem. Soc., 1953,75, 3662.
G. Olah, S. Kuhn, and M. Stelke,Chem. Ber., 1956,89, 2374.
G. Hetherington and R. L. Robinson,J. Chem. Soc., 1954, 3512.
US Pat. 3 071 438, 1963;Chem. Abstrs., 1963,59, 447.
B. S. Fedorov, Ph. D. (Chem.) Thesis, Inst. Chem. Phys. in Chernogolovka, Chernogolovka, 1976 (in Russian).
R.G. Gafurov, B. S. Fedorov, and L. T. Eremenko,Izv. Akad. Nauk SSSR, Ser. Khim., 1977, 383 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1977,26, 345 (Engl. Transl.)].
G. A. Sokol'skii and I. L. Knunyants,Izv. Akad. Nauk SSSR, Otd. Khim. Nauk [Bull. Acad. Sci. USSR, Div. Chem. Sci.], 1960, 779 (in Russian).
P. Gray and S. Smith,J. Chem. Soc., 1954, 769.
A. Vogel,J. Chem. Soc., 1948, 1847.
R. D. Silva,Ann., 1870,154, 256.
J. Bolleau and M. Thomas,Mém. poudres, 1951,33, 155.
Khimicheskaya entsiklopediya [Chemical Encyclopedia], Bol'shaya Rossiiskaya Entsiklopediya, Moscow, 1992,3, 270 (in Russian).
Spravochnik khimika [Chemist's Handbook], Goskhimizdat, Moscow, 1963,2 (in Russian).
N. Levy, C. W. Scaife, and A. E. W. Smith,J. Chem. Soc., 1946, 1096.
L. T. Eremenko and F. Ya. Natsibullin,Izv. Akad. Nauk SSSR, Ser. Khim., 1968, 912 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1968,17 (Engl. Transl.)].
L. T. Eremenko and G. V. Oreshko,Izv. Akad. Nauk SSSR, Ser. Khim., 1969, 384 (a); 320 (b) [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1969,18, No. 2 (Engl. Transl.)].
Z. M. Soffer, E. W. Parrotka, and J. D. Domenico,J. Am. Chem. Soc., 1952,74, 5301.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1059–1060, May, 1997.
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Fedorov, B.S., Eremenko, L.T. Nitration of alcohols by nitryl fluoride. Russ Chem Bull 46, 1022–1023 (1997). https://doi.org/10.1007/BF02496138
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DOI: https://doi.org/10.1007/BF02496138