Russian Chemical Bulletin

, Volume 46, Issue 5, pp 1018–1021 | Cite as

Synthesis and characteristics of novel pentanuclear complexes [(OC)3Mn(η15-C5H4)Fe(CO)215-C5H4CO2)]2M(η5-C5H5)2 (M=Ti, Zr)

  • T. Yu. Orlova
  • Yu. S. Nekrasov
  • P. V. Petrovskii
  • M. G. Ezernitskaya
  • B. V. Lokshin
  • M. Kh. Minacheva
  • L. A. Strunkina
  • O. L. Lependina
  • T. V. Magdesieva
  • S. V. Milovanov
  • K. P. Butin
Organometallic Chemistry

Abstract

The reaction of Cp2MCl2 complexes (M=Ti and Zr) with 2 equiv. of (OC)3Mn(η15-C5H4)Fe(CO)25-C5H4COONa) results in the formation of the pentanuclear complexes (OC)3Mn(η15-C5H4)Fe(CO)25-C5H4CO2)]2M(η5-C5H5)2, which are characterized by IR and1H NMR spectroscopy and cyclic voltammetry.

Key words

Group IV metal, polynuclear complex, synthesis IR spectra electrochemistry 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • T. Yu. Orlova
    • 1
  • Yu. S. Nekrasov
    • 1
  • P. V. Petrovskii
    • 1
  • M. G. Ezernitskaya
    • 1
  • B. V. Lokshin
    • 1
  • M. Kh. Minacheva
    • 1
  • L. A. Strunkina
    • 1
  • O. L. Lependina
    • 1
  • T. V. Magdesieva
    • 2
  • S. V. Milovanov
    • 2
  • K. P. Butin
    • 2
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation
  2. 2.Department of ChemistryM. V. Lomonosov Moscow State UniversityMoscowRussian Federation

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