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Synthesis, properties, and structures of ammonium 4-aryl-5-cyano-2-oxo-1,2,3,4-tetrahydropyridine-6-thiolates

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reaction of arylcyanomethylenethiocetamides with Meldrum, acid gave Michael adducts as ammonium salts. When heated in alcohol, these salts undergo cyclization to ammonium 4-aryl-5-cyano-2-oxo-1,2,3,4-tetrahydropyridine-6-thiolates. The structure ofN-methylmorpholinium 4-(2′-chlorophenyl)-5-cyano-2-oxo-1,2,3,4-tetrahydropyridine-6-thiolate was established by X-ray structural analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    V. N. Nesterov

  2. T. G. Shevchenko Lugansk State Pedagogical Institute, 2 ul. Oboronnaya, 348011, Lugansk, Ukraine

    S. G. Krivokolysko & V. V. Dotsenko

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    V. P. Litvinov

Authors
  1. V. N. Nesterov
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  2. S. G. Krivokolysko
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  3. V. V. Dotsenko
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  4. V. P. Litvinov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1029–1034, May, 1997.

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Nesterov, V.N., Krivokolysko, S.G., Dotsenko, V.V. et al. Synthesis, properties, and structures of ammonium 4-aryl-5-cyano-2-oxo-1,2,3,4-tetrahydropyridine-6-thiolates. Russ Chem Bull 46, 990–996 (1997). https://doi.org/10.1007/BF02496132

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  • DOI: https://doi.org/10.1007/BF02496132

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