Abstract
Novel styryl dyes containing dithia-15(18)-crown-6(5)-ether moieties were synthesized. Their selective complex formation with Hg2+ and Ag+ ions was studied by1H NMR and electronic spectroscopy; the stability constants of the Ag+ complexes and the relative stability constants (in relation to benzodithia-18-crown-6) of the Hg2+ complexes were determined. The chemical shifts of the \,\′-protons in the CH2S group change upon the complex formation in parallel with the logK 1 values of the complexes.
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For Part 20, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1007–1014, May, 1997.
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Gromov, S.P., Fedorova, O.A., Vedernikov, A.I. et al. Crown ether styryl dyes. Russ Chem Bull 46, 967–974 (1997). https://doi.org/10.1007/BF02496129
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DOI: https://doi.org/10.1007/BF02496129