Abstract
The retention of benzene derivatives in the normal-phase mode of high-performance liquid chromatography (HPLC) using a binary mobile phase (n-hexane-THF) on aminopropyl silica gel was considered. The possibility of describing the retention of the sorbates by known models was evaluated. It was established that molecular interactions between a sorbate and components of the mobile phase in solution can significantly affect the retention of the sorbates and the character of the dependence of the retention on the concentration of a modifier in the mobile phase. A quantitative description of this dependence was proposed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 987–991, May, 1997.
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Lanin, S.N., Ledenkova, M.Y. & Nikitin, Y.S. Retention of benzene derivatives on the aminopropyl stationary phase in high-performance liquid chromatography. Russ Chem Bull 46, 947–951 (1997). https://doi.org/10.1007/BF02496125
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DOI: https://doi.org/10.1007/BF02496125