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Raman spectra and molecular dynamics of R2NPX2 (R=Me and Et; X=F, Cl, and Br)

  • Physical Chemistry
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Abstract

The Raman spectra of compounds R2NPX2 (R=Me and Et; X=F, Cl, and Br) were studied. The time correlation functions of vibrational and rotational relaxations as well as the characteristic times of these processes were calculated. Conclusions concerning the mechanisms of formation of the contours of the Raman lines with frequencies in the 670–705 cm−1 range corresponding to the totally symmetric vibrations of the P-N bond in the R2NPX2 molecules were drawan.

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Authors and Affiliations

  1. State Scientific Center of Russian Federation “Kurchatov Institute”, 1 pl. I. V. Kurchatova, 123182, Moscow, Russian Federation

    Sh. Sh. Nabiev, I. I. Ostroukhova, N. V. Revina & L. P. Sukhanov

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  1. Sh. Sh. Nabiev
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  2. I. I. Ostroukhova
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  3. N. V. Revina
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  4. L. P. Sukhanov
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Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 5, pp. 961–967, May 1997.

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Nabiev, S.S., Ostroukhova, I.I., Revina, N.V. et al. Raman spectra and molecular dynamics of R2NPX2 (R=Me and Et; X=F, Cl, and Br). Russ Chem Bull 46, 921–927 (1997). https://doi.org/10.1007/BF02496120

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  • DOI: https://doi.org/10.1007/BF02496120

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