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Interaction of chromophores in dissimilar associates of cationic and anionic polymethine dyes in water

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A strong interaction between chromophores of cationic and anionic components was found based on the analysis of electronic absorption spectra of aqueous solutions of mixtures of cationic indopolycarbocyanines with anionic cyanines. Strong dissimilar 1∶1 associates are formed. Association constants were estimated spectrophotometrically. The main factors determining the degree of interaction of chromophores were revealed.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of the Ukraine, 5 ul. Murmanskaya, 253094, Kiev, Ukraine

    A. A. Ishchenko, N. A. Derevyanko, S. V. Popov & Yu. L. Slominskii

  2. Kharkov State University, 4 pl. Svobody, 310077, Khar'kov, Ukraine

    V. L. Koval', S. A. Shapovalov & N. O. Mchedlov-Petrosyan

Authors
  1. A. A. Ishchenko
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  2. N. A. Derevyanko
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  3. S. V. Popov
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  4. Yu. L. Slominskii
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  5. V. L. Koval'
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  6. S. A. Shapovalov
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  7. N. O. Mchedlov-Petrosyan
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 950–955, May, 1997.

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Ishchenko, A.A., Derevyanko, N.A., Popov, S.V. et al. Interaction of chromophores in dissimilar associates of cationic and anionic polymethine dyes in water. Russ Chem Bull 46, 910–915 (1997). https://doi.org/10.1007/BF02496118

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  • DOI: https://doi.org/10.1007/BF02496118

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